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Joseph
Henry | | | | |
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DOCUMENTS
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| .29. "RECORD OF EXPERIMENTS" |
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| | March
25th 1847 It
is mentioned by count Rumford in the Journal of the
Royal Institution
that the Introduction of balls of fine clay into a coal fire
increases the heat though the clay cannot
enterA into combustion and thus increase the heat.1 The idea at first
struck
me as rediculous but on reflection I found that there was a clear
physical
analogy to support the probability of the truth of the fact namely the
increase of light which is producd when a solid substance is intoduced
into the feebly luminous flame of a sperit lamp.
To test conclusively B
the truth of the proposition I put the thermo electrical apparatus in
order
and deflected the needle of the galvanometer by theC heat of a sperit
lamp
to the amount of 15 degrees the end of a platinum wire of about six
inches
in length was then coiled into the form of a spiral and plunged into
the
flame of the lamp the luminosity was of course considerably increased
while
at the same time the needle of the galvanometer moved from 15 to 27
degrees.
The truth of the proposition is therefore conclusively proved by this
experiment. But
was is theD cause of the phenomenon? is it due to
the fact of the
increase of the combination of the oxygen and hydrogen by the action of
the platinum on the principle of the action of the
flameless lamp2 or is it the result of the conversion of heat of less
radiating power into heat of greater.3 For a notice of Davy's new viws of flame see Brand
Vol 2
page 126 1817.
The heatE of flame may be diminished by increasing the light.4Henry
Papers, Smithsonian Archives. The final paragraph
is at the bottom of the page following a blank space and may be a later
addition. | | |
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| | 1 Benjamin Thompson, Count Rumford,
"Observations Relative
to the Means of Increasing the Quantities of Heat Obtained inthe
Combustion
of Fuel," Journals of the Royal Institution of Great Britain, 1802,
1:28-33.
A copy of this volume survives in the Henry Library, with an annotation
(p. 29) to Rumford's remark that there were no good quantitative data
regarding
the amount of heat thrown off by different substances when raised to
the
same temperature. |
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2 The flameless lamp was an
alcohol
lamp
with a fine platinum
wire coiled around the wick. Once the lamp was lit, the wire would
continue
to glow red hot even after the flame was extinguished. The theory of
the
flameless lamp was that the platinum wire retained enough heat to
continue
the combustion of the alcohol at a level sufficient to maintain the
temperature
of the wire but insufficient to reignite the alcohol. J. L. Comstock,
"Description
of the Aphlogistic Lamp," Silliman's Journal, 1822, 4:328-331. |
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3
Henry
summarized his thoughts
regarding Rumford's assertion
in the first two pages of a four-page memorandum,
"Speculations on Light and heat," tipped
into the "Record
of Experiments" between the March 25 and 26 entries. He made a
preliminary
report on his experiments proving the truth of Rumford's assertion to
the
American Philosophical Society in 1849, and a fuller account to the
American
Association for the Advancement of Science in 1855. APS Proceedings,
1848-1853,
5:108; "On the Effect of Mingling Radiating Substances with Combustible
Materials," AAAS Proceedings, 1855, 9:112-116.
In
"Speculations on Light and heat,"
Henry first hypothesized
that the cause of the increase of the heat was an increase in
combustion.
He laid out a number of experiments "for settling the question." The
first,
using thermoelectric apparatus, was conducted on this date.
We
have
not been able to document the others, which are comparisons of the
amount
of fuel burnt in given time periods with or without the platinum wire.
In the
second half of the memorandum,
however, Henry suggested
a different explanation. Spurred by the memory of a remark by Bache in
Washington "a few days ago," Henry speculated that introducing the
solid
matter shortened the wavelength of the radiant heat, increasing its
heating
power. His 1855 paper presented this explanation, relying upon
experiments
utilizing a spirit lamp, documented in the March 1847 "Record of
Experiments"
entries, and those using a hydrogen jet, for which we have not found
documentation.
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| 4
Humphry Davy, "Notice of Some
Experiments and New Views
Respecting Flame," Quarterly Journal of Science,
Literature, and Arts, 1817, 2:124-127.
Henry is paraphrasing
a supposition on page 127, one of six corollaries Davy drew
from his belief that the
brilliancy of
flame was due
to the production and ignition of solid matter within the flame.
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A
Altered
from entre B
Altered from conclusive C
Altered from a D
Altered from this E
Altered from l | | |
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